They were waiting _____ the station _____ twenty minutes.
They were waiting _____ the station _____ twenty minutes.
Explanation
"At the station": Indicates the location where they waited.
"For twenty minutes": Specifies the duration of waiting.
Use "at" for general locations (e.g., at the park, at home).
Use "for" to indicate duration (e.g., for hours, for days).